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Synchrotron Far-IR for MOF Morphology Changes

Appearing in the pages of the Journal of Physical Chemistry C this month is a collaboration between the Ennis and Meledandri workgroups interrogating the gas adsorption and thermal properties of Cu(II)BTC MOF nonparticles with synchrotron far-infrared and periodic DFT. Here we prevent peculiar, temperature dependent, structural changes between HKUST-1 polymorphs; revealed by low frequency lattice and torsional modes. Thanks to Subo Lee at Massey for some additional characterisation.

Read Here: Ennis, Tay, Falconer, Lee & Meledandri (2021) JPCC

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