{"id":98,"date":"2017-11-24T14:05:48","date_gmt":"2017-11-24T01:05:48","guid":{"rendered":"https:\/\/blogs.otago.ac.nz\/brooker\/?page_id=98"},"modified":"2018-10-02T14:24:41","modified_gmt":"2018-10-02T01:24:41","slug":"front-covers","status":"publish","type":"page","link":"https:\/\/blogs.otago.ac.nz\/brooker\/front-covers\/","title":{"rendered":"Front Covers"},"content":{"rendered":"

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R. W. Hogue,\u2020 S. Singh\u2020 and S. Brooker<\/strong>, Spin crossover in discrete polynuclear iron(II) complexes, Chemical Society Reviews, 47<\/em>, 7303-7338, 2018<\/strong> (open access), and inside front cover. DOI: 10.1039\/c7cs00835j<\/a> \u00a0\u2020Equal contributions from these two authors.<\/p>\n

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F. N. H. Karabulut, H. L. C. Feltham and S. Brooker, Substituents drive ligand rearrangements, giving dinuclear rather than mononuclear complexes, and tune CoII\/III<\/sup> redox potential, Dalton Transactions<\/em> (invited contribution, refereed as usual, to special issue \u2018frontiers in coordination chemistry and its applications\u2019 commemorating Prof Kim Dunbar\u2019s 60th<\/sup> birthday), 47<\/em>, 11749-11759, 2018<\/strong>, and front cover feature. DOI: 10.1039\/c8dt01502c.\u00a0(image generated by\u00a0Michael Crawford, Dunedin, from a concept provided by Sally Brooker)<\/p>\n

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R. W. Hogue, S. Dhers, R. M. Hellyer, J. Luo, G. S. Hanan, D. S. Larsen, A. L. Garden and S. Brooker, Self-assembly of cyclohelicate [M3<\/sub>L3<\/sub>] triangles over [M4<\/sub>L4<\/sub>] squares, despite near linear bis-terdentate L and octahedral M, Chemistry – A European Journal<\/em>, 2017<\/strong>, 23<\/em>, 14193\u201314199 \u2018hot paper\u2019 and front cover (with interview). DOI 10.1002\/chem.201702153.\u00a0(image generated by\u00a0Michael Crawford, Dunedin, from a concept provided by Sally Brooker)<\/p>\n

Ross Hogue ChemEurJ Interview<\/a><\/p>\n

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Humphrey Feltham ChemEurJ Interview 2017<\/a><\/p>\n

H. L. C. Feltham, C. Dumas, M. Mannini, E. Otero, P. Sainctavit, R. Sessoli, C. J. Meledandri and S. Brooker, Proof of principle: immobilisation of robust CuII<\/sup>3<\/sub>TbIII <\/sup>macrocycles on small, suitably pre-functionalised gold nanoparticles, Chemistry \u2013 A European Journal<\/em>, 2017<\/strong>, 23<\/em>, 2517\u20132521, \u2018hot paper\u2019 and front cover (with interview). DOI: 10.1002\/chem.201604821.\u00a0(image generated by\u00a0Michael Crawford, Dunedin, from a concept provided by Sally Brooker)<\/p>\n

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S. Rodr\u00edguez-Jime\u0301nez, H. L. C. Feltham and S. Brooker, Non-porous iron(II)-based sensor: crystallographic insights into a cycle of colorful guest-induced topotactic transformations, Angewandte Chemie International Edition<\/em>, 2016<\/strong>, 55<\/em>, 15067\u201315071, and outside back cover. DOI: 10.1002\/anie.201608813.\u00a0(image generated by\u00a0Michael Crawford, Dunedin, from a concept provided by Sally Brooker)<\/p>\n

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A. Thevenon, C. Romain, M. S. Bennington, A. J. P. White, H. J. Davidson,
\nS. Brooker and C. K. Williams,\u00a0Di-zinc lactide polymerization catalysts: hyper-activity by control of ligand conformation and metallic cooperativity,\u00a0Angewandte Chemie International Edition<\/em>, 2016<\/strong>, 55, 8680-8685,\u00a0and inside front cover. Hot paper. DOI: 10.1002\/anie.201602930 (open access<\/a>).\u00a0(image generated by\u00a0Michael Crawford, Dunedin, from a concept provided by Sally Brooker)<\/p>\n

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R. G. Miller and S. Brooker,\u00a0Reversible quantitative guest sensing via spin crossover of an iron(II) triazole,\u00a0Chemical Science<\/em>, 2016<\/strong>, 7<\/em>, 2501-2505, and front cover feature. DOI: 10.1039\/C5SC04583E\u00a0(open access<\/a>)\u00a0(image generated by\u00a0Michael Crawford, Dunedin, from a concept provided by Sally Brooker)<\/p>\n

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R. G. Miller, S. Narayanaswamy, S. M. Clark, G. B. Jameson, J. L. Tallon and S. Brooker,\u00a0Pressure induced separation of phase-transition-triggered-abrupt vs gradual components of spin crossover,\u00a0Dalton Transactions, 2015<\/strong>, 44<\/em>, 20843-20849. DOI: 10.1039\/C5DT03795F.\u00a0(image generated by\u00a0Michael Crawford, Dunedin, from a concept provided by Sally Brooker)<\/p>\n

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H.L.C. Feltham, S. Dhers, M. Rouzi\u00e8res, R. Cl\u00e9rac, A.K. Powell and S. Brooker,
\nA family of fourteen stable soluble macrocyclic [NiII<\/sup>3<\/sub>LnIII<\/sup>] complexes,
\nInorganic Chemistry Frontiers (invited contribution to a special issue on magnetism, refereed as usual)\u00a02015<\/strong>, 2<\/em>, 982-990. DOI: 10.1039\/C5QI00130G.\u00a0(image generated by\u00a0Michael Crawford, Dunedin from a concept provided by Sally Brooker)<\/p>\n

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S. Brooker,\u00a0“Spin crossover with thermal hysteresis: practicalities and lessons learnt”,\u00a0Chem. Soc. Rev.<\/em>\u00a02015<\/strong>, 2015, 44, 2880-2892.\u00a0Cover created by Lucy R. Brooker (Christchurch) and fine-tuned by Michael Crawford (Dunedin) from a concept provided by Sally Brooker.<\/p>\n

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“Doubling the anion occupancy in the channels of the metal organic framework (NiII<\/sup>-based MOF \u2192 CoIII<\/sup>-based MOF)\u00a0increases the observed adsorption selectivity for CO2<\/sub>\u00a0over N2<\/sub>. These robust isostructural MOFs were assembled using AgBF4<\/sub>
\nto activate the secondary coordination instructions present in the carefully designed monometallic pyrazine imide complexes of nickel(II) and cobalt(II or III).
\nCover created by Michael Crawford (Dunedin) from a concept provided by Sally Brooker.”\u00a0 See our 2014 paper in\u00a0Inorganic Chemistry<\/em>:
\nM. G. Cowan, R. G. Miller, P. D. Southon, J. R. Price, O. Yazaydin, J. R. Lane, C. J. Kepert, and S. Brooker,\u00a0Inorg. Chem.<\/em>\u00a02014<\/strong>, 53<\/em>, 12076-12083.<\/p>\n

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Brooker, S., Plieger, P.G., Moubaraki, B. and Murray, K.S., [CoII<\/sup>2<\/sub>L(NCS)2<\/sub>(SCN)2<\/sub>]:
\nThe first cobalt complex to exhibit both exchange coupling and spin crossover effects,
\nAngewandte Chemie International Edition<\/i>, 38, 408-410 and front cover feature (1999).\u00a0Cover created by Michael Crawford (Dunedin) from a concept provided by Sally Brooker.<\/p>\n

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Brooker, S., Some Copper and Cobalt Complexes of Schiff-base
\nMacrocycles Containing Pyridazine Head Units, European Journal of Inorganic Chemistry,\u00a0(invited microreview contribution, refereed as usual), 2535-2547 and front cover feature (2002).\u00a0Cover created by Michael Crawford (Dunedin) from a concept provided by Sally Brooker.<\/p>\n

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Lan, Y., Kennepohl, D.K., Moubaraki, B., Murray, K.S., Cashion, J.D., Jameson, G.B. and Brooker, S.,\u00a0Coordination algorithms control molecular architecture: [CuI4(L2)4]4+ grid complex versus [MII2(L2)2X4]y+ side-by-side complexes (M = Mn, Co, Ni, Zn; X = solvent or anion) and [FeII(L2)3][Cl3FeIIIOFeIIICl3],\u00a0Chem. Eur. J.<\/em>, 9, 3772-3784, and front cover feature (2003<\/strong>).\u00a0Cover created by Michael Crawford (Dunedin) from a concept provided by Sally Brooker.<\/p>\n

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Klingele, M.H., Moubaraki, B., Cashion, J.D., Murray, K.S. and Brooker, S.,
\nThe first X-ray crystal structure determination of a dinuclear complex trapped in the [low spin-high spin] state: FeII2(PMAT)2](BF4)4\u00b7DMF, Chemical Communications, 987-989,
\nidentified as a \u201chot paper\u201d (top 10%) and featured on the front cover of issue 8, February (2005<\/strong>).\u00a0Cover created by Michael Crawford (Dunedin) from a concept provided by Sally Brooker.<\/p>\n

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Price, J.R., Lan, Y., Jameson, G.B. and Brooker, S.,\u00a0Control of molecular architecture by steric and electronic factors: dinuclear side-by-side vs tetranuclear [2×2] grid-type silver(I) complexes,\u00a0Dalton Transactions, 1491-1494, and front cover feature (2006<\/strong>).\u00a0Cover created by Michael Crawford (Dunedin) from a concept provided by Sally Brooker.<\/p>\n

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Klingele (nee Hausmann), J., Boas, J.F., Pilbrow, J.R., Moubaraki, B., Murray, K.S.,
\nBerry, K.J., Hunter, K.A., Jameson, G.B., Boyd, P.D.W.and Brooker, S.
\n[2 \u00d7 2] nickel(ii) grid and a copper(ii) square result from differing binding modes of a pyrazine-based diamide ligand,\u00a0Dalton Transactions<\/em>, 633-645 (2007<\/strong>); and front cover feature.\u00a0\u201cOne of Dalton Transactions\u2019 most highly rated articles\u201d, i.e. \u201chottest science, as recommended by the referees\u201d.\u00a0Cover created by Michael Crawford (Dunedin) from a concept provided by Sally Brooker.<\/p>\n

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Brandt, C.D., Kitchen, J.A., Beckmann, U., White, N.G, Jameson, G.B. and Brooker, S.,Synthesis and structures of 3,5-disubstituted 1,2,4-triazole head units and incorporation of 3,5-dibenzoyl-1,2,4-triazolate\u00a0into new [2+2] Schiff-base macrocyclic complexes,\u00a0Supramolecular Chemistry<\/em>\u00a0(invited contribution to a special International
\nSymposium on Macrocyclic and Supramolecular Chemistry issue, refereed as usual), 19, 17-27, and contribution to front cover feature (2007<\/strong>).<\/p>\n

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Price, J.R., Lan Y., Brooker, S.,Pyridazine-bridged copper(I) complexes of bis-bidentate ligands: tetranuclear [2 x 2] grid versus dinuclear side-by-side architectures\u00a0as a function of ligand substituents,\u00a0Dalton Transactions<\/em>, 1807-1820 and front cover feature (2007<\/strong>).\u00a0\u201cOne of Dalton Transactions’ most highly rated articles\u201d, i.e. \u201chottest science, as recommended by the referees\u201d.\u00a0Cover created by Michael Crawford (Dunedin) from a concept provided by Sally Brooker.<\/p>\n

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Grunert, C.M., Reiman, S., Spiering, H., Kitchen, J.A., Brooker, S. and G\u00fctlich, P.,
\nMixed spin-state [HS-LS] pairs in a dinuclear spin-transition complex: confirmation by variable temperature 57Fe M\u00f6ssbauer spectroscopy,\u00a0Angewandte Chemie International Edition<\/em>, 47, 2997-2999, and front cover feature (2008<\/strong>).\u00a0Cover created by Michael Crawford (Dunedin) from a concept provided by Sally Brooker.<\/p>\n

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Lan, Y., Novitchi, G., Cl\u00e9rac, R., Tang, J.K., Madhu, N.T., Hewitt, I.J., Anson, C.E., Brooker, S. and Powell, A.K.,\u00a0Di-, tetra- and hexanuclear iron(III), manganese(II\/III) and copper(II) complexes of Schiff-base ligands derived from 6-substituted-2-formylphenols,\u00a0Dalton Transactions, 1721-1727 (2009<\/strong>), and front cover feature. Cover created by Sarah White.<\/p>\n

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Brooker, S., and Kitchen, J.A., Nano-magnetic materials: spin crossover compounds vs. single molecule magnets vs. single chain magnets,\u00a0Dalton Transactions<\/em> (invited Frontier Article, refereed as usual), 7331-7340 (2009<\/strong>).\u00a0Cover created by Michael Crawford (Dunedin) from a concept provided by Sally Brooker.<\/p>\n

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Kitchen, J.A. and Brooker, S.,\u00a0Two dicobalt(III) complexes of triazolate-containing [2+2] Schiff-base macrocycles coordinate thiocyanate ions via the sulphur atom,\u00a0Dalton Transactions<\/em>,\u00a039<\/em>, 3358-3360 (2010<\/strong>). DOI: 10.1039\/B925745D.\u00a0Cover created by Michael Crawford (Dunedin) from a concept provided by Sally Brooker.<\/p>\n

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Feltham, H.L.C., Lan, Y., Kl\u00f6wer, F., Ungur, L., Chibotaru, L.F., Powell, A.K. and Brooker, S.,A non-sandwiched macrocyclic mono-lanthanide single molecule magnet: the key role of axiality,\u00a0Chemistry – A European Journal<\/em>,\u00a017<\/em>, 4362-4365 (2011<\/strong>) and cover feature. DOI: 10.1002\/chem.201100438.\u00a0Cover created by Michael Crawford (Dunedin) from a concept provided by Sally Brooker.<\/p>\n

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Olgu\u00edn, J., and Brooker, S.,\u00a0Synthesis of 3- and 5-formyl-4-phenyl-1H-pyrazoles: promising head units for the generation of asymmetric\u00a0imine ligands and mixed metal polynuclear complexes,\u00a0New Journal of Chemistry<\/em>,\u00a035<\/strong>, 1242-1253 (2011). DOI: 10.1039\/C0NJ00774A.\u00a0Cover created by Michael Crawford (Dunedin) from a concept provided by Sally Brooker.<\/p>\n

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Cowan, M.G and Brooker, S.,\u00a0\u00a0Nine non-symmetric pyrazine-pyridine imide-based complexes: reversible redox and isolation of [MII\/III<\/sup>(pypzca)2<\/sub>]0\/+<\/sup>\u00a0when M = Co, Fe
\nDalton Transactions<\/em>, 2012, 41, 1465-1474. DOI:10.1039\/C1DT11128K
\nhttp:\/\/www.rsc.org\/Publishing\/Journals\/an\/article.asp?doi=C1DT11128K<\/a>\u00a0Cover created by Michael Crawford (Dunedin) from a concept provided by Sally Brooker.<\/p>\n

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Cowan, M.G., Olgu\u00edn, J., Narayanaswamy, S., Tallon, J.L., and Brooker, S.,
\nReversible switching of a cobalt complex by thermal, pressure and electrochemical stimuli: abrupt, complete, hysteretic spin crossover
\nJournal of the American Chemical Society, 2012, 134, 2892-2894.\u00a0http:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/ja208429u<\/a>\u00a0\u00a0Cover created by Michael Crawford (Dunedin) from a concept provided by Sally Brooker.<\/p>\n","protected":false},"excerpt":{"rendered":"

  R. W. Hogue,\u2020 S. Singh\u2020 and S. Brooker, Spin crossover in discrete polynuclear iron(II) complexes, Chemical Society Reviews, 47, 7303-7338, 2018 (open access), and inside front cover. DOI: 10.1039\/c7cs00835j \u00a0\u2020Equal contributions from these two authors. F. N. H. Karabulut, […]<\/p>\n","protected":false},"author":96,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"class_list":["post-98","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/blogs.otago.ac.nz\/brooker\/wp-json\/wp\/v2\/pages\/98","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/blogs.otago.ac.nz\/brooker\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/blogs.otago.ac.nz\/brooker\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/blogs.otago.ac.nz\/brooker\/wp-json\/wp\/v2\/users\/96"}],"replies":[{"embeddable":true,"href":"https:\/\/blogs.otago.ac.nz\/brooker\/wp-json\/wp\/v2\/comments?post=98"}],"version-history":[{"count":0,"href":"https:\/\/blogs.otago.ac.nz\/brooker\/wp-json\/wp\/v2\/pages\/98\/revisions"}],"wp:attachment":[{"href":"https:\/\/blogs.otago.ac.nz\/brooker\/wp-json\/wp\/v2\/media?parent=98"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}